You can print a multipage document as a booklet. Acrobat or Reader lays out the pages two per sheet. When you collate, fold, and staple the double-sided sheets, the result is a single book with the correct page order.
Multipage PDF printed as a booklet: four pages per sheet, printed both sides, left-side binding.
In the Booklet Subset pop-up menu, select one of the following options: Both sides (duplex printers) automatically prints both sides of the paper, if your printer supports automatic duplex printing. Front side only / Back side only (for non-duplex printers) If your printer can’t automatically print both sides, you can first print the front sides of the paper. Then reload those pages and print the back sides.