Locate AdobeCaptivate.exe in your installation directory. If you have not changed any settings during installation, you can locate this in the \\Program Files\Adobe\Adobe Captivate Classic <version_number> folder.
How to record applications having elevated permissions in Windows Vista or Windows 7
You will have to set administrator permissions for the AdobeCaptivate.exe file to record or capture applications running in elevated or administrator mode.
To set administrator permissions for AdobeCaptivate.exe:
Right-click the file, and select Run As Administrator. The User Account Control (UAC) dialog box appears.