Quit Dreamweaver.
Perform the following steps:
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In Spotlight, type "Keychain." Locate the "Keychain Access" application and launch it.
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Keychain Access lists the Keychain items. In the "Name" column, locate the item that has the name of the site you are trying to troubleshoot in Dreamweaver.
For example, "SiteName-SiteServer 0". The corresponding entry in the "Kind" column reads "application password."
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Click the item to select it. The properties of the Keychain item appear at the top of the Keychain Access window. As a double check, ensure that the value shown for "Account" is the FTP user name. If it's not, then you may have selected the wrong item.
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After ensuring that you have selected the right Keychain item, press the Delete key to remove the item. Leave the application open for now.
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Launch Dreamweaver and go to the "Manage Sites" dialog box (Site > Manage Sites). Select the site that you are trying to troubleshoot and click the edit icon.
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Click Servers on the left and double-click the server name in the list to edit it.
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Enter the FTP user name and password, and then click Save to close the Edit Server box. Click Save again to close the Edit Site box.
In Keychain Access, a new Keychain item is created with the same name as the one you deleted earlier.
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Quit Keychain Access and Dreamweaver.
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Restart Dreamweaver and check if the FTP credentials are retained.